Since this triangle was cut w/the NN rulers it has a blunted point, but that's OK just imagine the point is still there and make the other point match up w/the edges. As in the photo.
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Then match up the pins or centers. You will have a point hanging off on one end and not the other. Your 1/4" seam should start right where the point starts to hang off the edge, and should finish right off the blunted off point on the other end. See Photo.
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Do this w/each edge. Usually I do the two opposite sides, press and then do the other two.
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Your finished Square in a Square should be nice and square.
Happy QuiLtInG!